Facile recycling of polyethene and polyethene terephthalate waste into wax and composite tiles

Authors

  • Prof. Moriam Dasola Adeoye Fountain University, Osogbo
  • Kafayat Adegbore Fountain University, Osogbo
  • Lukmon Jinadu Fountain University, Osogbo
  • Hanif Taofeek-Azeez Fountain University, Osogbo
  • Opeyemi Ojo Mountain Top University image/svg+xml
  • Raimot Ojedokun Fountain University, Osogbo

DOI:

https://doi.org/10.53704/

Keywords:

PET,, DSC,, Composite tiles, Flammability, Adsorption, Recycling

Abstract

The use of polyethene (PE) in packaging has always been associated with attendant environmental issues. Waste PE was sorted and processed from Fountain University, Osogbo, Osun State, Nigeria. For analysis, bottled water packaging, and nylon water sachets (PE) made of polyethene terephthalate (PET) were cleaned, dried, shredded, and characterised using X-ray diffraction (XRD), differential scanning calorimetry (DSC), and Fourier transform infrared (FT-IR) techniques. Two types of candle waxes (A and B) of different grades 1-4 labelled as (A1–A4), (B1 – B4) and composite tiles A and B (CTAs and CTBs) were made using egg shells as a source of calcium carbonate. Thermal recycling was done by combining PE with stearic acid (SA). O-H stretching bands were detected by FT-IR at 3457 cm-1 (A) and 3449 cm-1 (B), while PE peaks were observed at 2918 cm-1 and 720 cm-1, due to -C-H stretching. The wax characteristics, indicated by the endothermic peaks, were detected by DSC (94.5 °C for A and 99 °C for B). The candles' qualities were improved by additives. The hot- and cold-water absorption and flammability of the egg-shell-incorporated composite tiles exhibit favourable characteristics, with superior water and heat resistance, compared with the commercial tiles. The blends of SA and PE enhanced the candle performances. This study demonstrated the feasibility of repurposing the waste PE into economically viable products, candles and tiles, and supported the idea of “waste to wealth

Author Biography

  • Prof. Moriam Dasola Adeoye, Fountain University, Osogbo

    Chemical Sciences Department

References

1. Vijayalakshmi, M (2020). Modern Waste Management Tecniques – A critical Review. IOC-2020 Innovation and Sustainability through E-Stem - 14th & 15th October, 2020 ISBN: 978-93-88568-22-7 Published by Dr.M.G.R. Educational and Research Institute.

2. Fadhullah, W., Nor I. N. I., Sharifah N. S. I., Mohd, H. J. and Hasmah, A. (2022). Household solid waste management practices and perceptions among residents in the East Coast of Malaysia. BMC Public Health 22:1-20.

3. Ebikapade, A. and Baird, J. (2016). The Concept of Waste and Waste Management. Journal of Management and Sustainability; Published by Canadian Center of Science and Education 6 (4): 88 - 96 URL: http://dx.doi.org/10.5539/jms.v6n4p88 ISSN 1925-4725 E-ISSN 1925-4733.

4. Ezeugo, J. O., Onukwuli, O. D. and Ubaezuonu, C.P. (2018) . Laboratory Conversion of Used Water Satchet as A Regenerative Resources for Candle Wax Production. International Journal of Scientific and Management Research 1 (3) : 13-19. ISSN: 2581-6888

5. Alok B., Divyanshu, Y., Shreyshi, V. (2015). Non-Biodegradable Waste - Its Impact & Safe Disposal `International Journal of Advanced Technology in Engineering and Science 3(1): 184 – 191.

6. GodFred, L. (2019). Waste plastic, the challenge facing Developing Countries-Ban it, Change it, Collect it Recycling 4(1), 3

7. Nwofe, P. A (2013), Comparative Analysis of Domestic Energy use in Nigeria- A review. Continental J. Renewable Energy 4 (1): 7 – 17, 2013 © Wilolud Journal

8. Ayodeji P. I., Biodun, O. and Isaac, T. R. (2017) "Students’ attitudes to solid waste management in a Nigerian university: Implications for campus-based sustainability education", International Journal of Sustainability in Higher Education, Vol. 18 Issue: 7, pp.1244-1262, https:// doi.org/10.1108/IJSHE-03-2016-0057 Permanent link to this document: https://doi.org/10.1108/IJSHE-03-2016-0057 Downloaded on: 07 November 2017, At: 12:48 (PT)

9. Anierobi, C. and Efobi, K., (2013). Waste Pickers and Urban Solid Waste Management System in Nigerian cities: Between Sustainable Policy gap and Survivalist Strategy. www.iiste.org

10. Joseph, T. M., Hasanin, M. S., Unni, A. B., Kar Mahapatra, D., Haponiuk, J. and Thomas, S. (2023). Macromolecules: Contemporary Futurist Thoughts on Progressive Journey. Eng. 4: 678-702.

11. Muck and Brass The waste business smells of money’’ the economist. (2009) (02) 28 1012.

12. Ni, H. G., Lu, S. Y., Mo, T. and Zeng, H. (2016). Brominated flame retardant emissions from the open burning of five plastic wastes and implications for environmental exposure in China. Environmental Pollution. 214:70–76. https://doi.org/10.1016/j.envpol.2016.03. 049.

13. Jin, K., Vozka, P., Kilaz, G., Chen, W. T. and Wang, N. H. L. (2020). Conversion of polyethene waste into clean fuels and waxes via hydrothermal processing (HTP). Fuel, 273:117726. doi:10.1016/j. fuel .2020.117726

14. Bragg, W.L. (1934). The Crystalline State, Vol. 1, New York; The Macmillan Company.

15. Ozioko R. E., Ogbonna I. D., Ugwu K. C. (2018). Determination of the Melting Point of Paraffin Wax Using Temperature Variation Test Method. American Journal of Engineering Research (AJER) American Journal of Engineering Research (AJER) E-ISSN: 2320-0847 p-ISSN: 2320-0936 Volume-7 (12): 101-104.

16. Gönen, M., Balköse, D., Inal, F., and Ülkü, S., (2008). The effect of zinc stearate on thermal degradation of paraffin wax. Journal of Thermal Analysis and Calorimetry, Vol. 94 (3): 737-742.

17. Dang W, Bin Ni, Yujie Liu, Sheng Chen and Hailiang Zhang. (2015). Preparation and characterization of side-chain liquid crystal polymer/paraffin composites to form stable phase change materials. Journal of Materials Chemistry A. 3, 9645. DOI: 10.1039/c5ta00606f

18. Liang, C-J; Liao, J-D; Li, A-J; Chen, C.; Lin, H-Y; Wang, X-J; X, Y-H. (2014). Relationship between wettabilities and chemical compositions of candle soots Fuels, 128, 422-427.

19. Furlong, A. Haelssig, J. & Pegg, M. (2023). Impact of candle wicks and fuels on burning rate, flame shape, and melt pool diameter. Combustion and Flame. 249. 10.1016/j.combustflame.2023.112628.

20. Raju, M. & T'ien, J. (2008). Modelling of candle burning with a self-trimmed wick. Combustion Theory and Modelling - COMBUST THEORY MODEL. 12. 367-388. 10.1080/13647830701824171.

Downloads

Published

2025-11-24

How to Cite

Facile recycling of polyethene and polyethene terephthalate waste into wax and composite tiles. (2025). Fountain Journal of Natural and Applied Sciences, 14(1). https://doi.org/10.53704/

Similar Articles

You may also start an advanced similarity search for this article.